The Pesticide Contamination in the Paraná 3 Basin: Implications for Water Quality Management from a Systematic Review
Implications for Water Quality Management from a Systematic Review
Abstract
This systematic review provides the first integrated assessment of pesticide contamination and water quality in the Paraná 3 Basin, a transboundary agricultural watershed along the Brazil–Paraguay border that supplies the Itaipu hydroelectric reservoir. Using the ProKnow-C methodology, 26 studies were selected from 8,688 records, revealing that only 15.4% directly address the basin, a pronounced disparity between the region's strategic relevance and dedicated scientific output. Thematic analysis shows that glyphosate was detected in 19.3% and AMPA in 21.8% of surface-water samples, with peak concentrations linked to rainfall-driven runoff; atrazine and unregulated transformation products were also identified. Despite this evidence, targeted chromatographic monitoring and operational predictive models remain underrepresented. The most frequently identified gaps include the lack of binational regulatory harmonization (38% of studies), insufficient hydrological and land-use data (31%), and the absence of continuous long-term monitoring (23%). Ultimately, this review provides evidence to support basin-scale management and transboundary governance by recommending the establishment of standardized bilateral monitoring protocols, the development of open georeferenced environmental databases, and the incorporation of predictive modeling for evidence-based decision-making
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